In order to provide a more convenient and economical approach of graphene synthesis on semiconducting 6H-SiC, commercially available single crystalline 6H-SiC samples were implanted at room temperature with 5 keV carbon ions. The prepared samples were characterized by Raman spectroscopy, scanning electron microscope (SEM) and atomic force microscope (AFM). Moreover, the influences of cooling rates and the enclosed environment were investigated. A possible growth mechanism based on the Si sublimation was also put forward to explain the graphene growth. The results show that the graphite enclosure effectively control the Si sublimation and the cooling rate affects the precipitation and surface self-assembly of C atoms. Upon proper cooling, the implanted carbon atoms segregate to the surface and self-assemble into bilayer or multilayer graphene on 6H-SiC. This method reduces the annealing temperature to 1100℃ in vacuum condition without hydrogen etching, ultrahigh vacuum or special atmosphere, which is more cost-effective and efficient.